Apparatus for and method of concentrating sulfuric acid.



J PATTEN. APPARATUS FOR AND METHH) 0F CONCE-NTRATING SULFURIC ACID, APPLICATION FILED oct.2'4-. 19w. 1 24 9 Y 2 257 I Patented Feb. 18, 1919.

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[NVENTOR W TNESSES J. PATTEH. APPARATUS FOR AND J'IETHQD 0F CONCENTRAHNG SULFUR: As).

I APPLICAHQN FILED OCT. 24, iQIY- v p L ifii ii Patented 510%), 28, 1919,

5 SHEETS-SHEE 2- ggS F Y HZVENTOF J. PATTEN. I APPARATUS FOR AND METHOD 0? CQNCENTRATING SULFURIC ACID.

4, p K m APPUCATIDH HLFD OCT. 24, 1917 D A,9-,@Q iatented Feb. 18, 1919.

5 SHEETS-SHEET 3.

' sicueg J. PATTEN. APPARATUS FOR AND METHOD OF CONCENTRATING SULFURIC ACID.

m N4 in Wi h m es Fm E H s ws n m P 4 APPLICATION FILED OCT. 24. I917. LQQQEQT.

rl ll HS J on IIIIIIIU ilwim if NTOR i I h time JOHN FATTIEN, OE BALTIMSL E,

- resent es ECCLESZOEI, imiswieii FOB AED METHDIO O15 '"ONCENTEAZIHG 520;???)

Application filed flctober 24, 1917.

T0 aZZ whom it may concewn:

Be it known that 1, JOHN PATTEN, a citizen of the United States, and a resident of Baltimore city, of Maryland, have inrented certain new and useful lihpro' emetots in Apparatus for and Methods of Concentrating Suiiuric Aciii; and I do hereby declare the foilewiug to be a fuli, clear, and

exact description of the invention, such as will eiiehie others skiiled in the art te Wdifiil it apperteins to make and use the 8111116:

This invention relates t0 improvements in apparatus for and the niethod'of concentrating suiiurie a cid,one object of the invention being to prevent the escape and dissipation of noxious fumes into the etmoss phere, and thus overcome the disastrous e'i feet upon vegetation heretofore encountered in the vicinity of plants Where sui'furic acid is concentrated,

A further object is to so construct the apparatus that the sphising incident to the concentration of sulfuric acid, she-ii be confined Within the vessels in which the con centration is effected, and thus protect the framework of the apparatus from the injurious effect of the acid, and also saving a con sideruhie quantity of acid which has heretofore been iost by escape with the fumes.

A further object is to construct the apye ratus in such manner that the Water wiii he so evuporeteci from the acid that any acid which um tend to escape uh the aqueous vapor shah he separated I the hitter ahci returned to the body of H t in the CODCQH. treters, thus preventing t e escape e' hurt- 1 11i quantities of acid per and permittiiig erect a suiiieient degree of puri 'y to eapehie of emoieyineiit for an}; 1

in} purpose, or to he concieused or dio cherg i into the .tiflfiiil i'ere Wiiilfiilil deleterious upon suriuuiieing vegetation.

A further object is to construct and operate the apparatus in a manner to economize fuel and at'the same time maintain a groper degree 01"- heat to effect desired concentrw tion of the acid.

A further object is to so construct the per'etus that during the operation of the Specification of letters Patent.

MARYLAND, ASSIGNDE 035 613"" 1 "3 33 4 $1 ecu, hem/w,

Serial No. 198E522.

same, portions of the products of combustion 2 under the condensing; raters, may be u i E same with the hot ever the fire chm ereture of suc reach the comic-11 rators, whereby such containers or cehcentretcrs pensstion for con "an and may be prevideii .ABZ; Witheut c ieeizage, and so that anyone seic tiuners may he reiiieved when bro repieeeti by new one, Without any o her at iither eh iect is to censtru he apparatus in such may highesttemperature the a 1 and pie o: combustion from. the furnace sheii he plied the end of a series 01? contain concentrators Where the Week ec ciuceci, end else the: thetempereture e ir and iireducts combustion Wiii e rapidly as they'tmvei to the other end 0; the "01's 1 mm series oi containers or eoncei which he strong acid is deiivere A further object is (G j means whereby M atus may he oth r his r'itus emhoiiyiiig my improvements; 2. is a treiisveise seetienei View, through a but tery QT? units, enei showing seetions on tines L I-fi, G Q and i9-i3 ozti is e. sect-ion on the iine E m 0f is sectieii oh the line i -i 1; Fig. 6 is section on the line H H of Fig. 1; Figs. 7, 8 and 9 are enlarged detail views showing the discharg 'levices and portions of the automatic teed control means, and 10, 11 and 12 are enlarged detail views showing the concentrators.

in apparatus of the character to which my invention relates, it is customary to provide a plurality or battery of units and these may e so built to provide a unitary structure, as a whole, as indicz'ited in Fig. 2. As these units and the various instrumeutalities which therein. are identical in construction, a specific description of one unit will sutllce for all of them.

1 represents the masonry of a' furnace structure, the combustion chamber 2 of which is separated from the ash pit 3 by a suitable grate a on which the fuel is supported. The combustion chamber may be provided with a suitable door 5 and a door opening communicating with the ash pit will serve to admit air to provide a suitable draft through the furnace. A bridge wall 6 is built within the furnace structure and provides several passages or fines 7, 8, 9 and 10 or the travel of hot products of combustion. The passage 7 is located directly over the combustion chamber and its large lower portion communicates with the latter through contracted opening 11 and in order to cause the products of combustion to enter the passage 7 in the form of a plurality oi? streams-l employ a plurality of spaced bars 12 of fireproof material, directly over the opening 11. The bridge wall is ot' such term that a contracted passage 13 will connect the upper end of the passage 7 at the left hand end of the furnace structure with the inclined passage S,the other end or" the latter communicating with the vertical passage the right hand end of the furnace structure, and said vertical passage 9 communicates at its lower end with one end of the horizontal passage 10in the bottom portion of the furnace structure. The other end of the bottom passage 10 communicates through a contracted opening 14 with the passage E a plurality of spaced bars 15 being located in said opening to cause the products of combustion to enter the passage '7 in several streams to inti- *i'llil'CGlf/ comming'le with the streams of. hotter products of combustion flowing into said iassage i from the combustion chamber.

The passage 8 also communicates. through a line 15 with stack ll and the draft through the stack may be regulated and controlled by means or a damper 18 (Figs. 1 and 2) controlled by suitable manually his dam er may be when it desired to stop the opera- 'tion' of the apparat l:

5 a section on the line G t ot' The top of the bridge wall 6 is mal inclined so as to slant downwardly toward the right hand or discharge end of the apparatus, the upper face of said wall being dished to form a gutter 20 to receive any acid which might escape from containers or condensers 21 disposed over said wall, in.

the event of leakage or breakage of any of said containers or concentrators. Such escaping-acid would flow down over the end of the bridge wall and into, a trough 22 in the bottom of the furnace structure and from the latter trough, the escaping acid will ilow through an opening 23 in a door 24 and become deposited into an exterior trough 25 which may convey it to a suitable receptacle, not shown.

The concentrators 21 are arranged in a connected series in two rows disposed in a diagonal position above the inclined top of the bridge wall and form, in effect, a large portion of the top of flue or passage 8. The concentrators 21 are individually supported, so that any one of them may be removed when broken. and replaced by a new one without disturbing any of the others. Thus the condensers or concentrators are suspended by means of hangers 26 from transverse bars 27 mounted on the walls of the furnace structure above the fire brick. said hangers being made in the form of bails having the lower ends of their respective members bent inwardly into perforations in lugs 28 on the concentrators. I

An opening 28* (normally closed by a door 28*) may be providedin the wall of the furnace structure to permit inspection of the concentrators.

The concentrators are made of suitable acid proof material, such for example, as an alloy or iron and silicon, and are made in such form that the acid under treatment. will be so confined as to prevent the splashing from reaching other parts of the apparatus. I prefer to make theconcentrators spherical in form as clearly shown in Figs. 10, 11 and 12.

Each concentrator is made with two openings 29 and 30 which are disposed at approximately right angles to each other. An elbow nozzle 31 is cast integral with the concentrator coincident with the opening 29 and a flange 32 is formed around the open-' ing 30. The free end portion ofthe elbow nozzle 81 of one concentrator enters the opening 30 of the adjacent -concentrator and a ball joint 33 is formed between said nozzle elbow and the flange 32 of such adjacent concentrator. The flange 32 is formed with shoulders 34 for the reception of the hooked or flanged ends of a bail which latter embraces the elbow nozzle. An adjusting screw 36 passes through the free end of the bail and between the inner end of this recess? lbow nozzle, 7 -hapcd in disco i. 3; construction, insconcentrators will. be connects:

as to compensate for expansuch slip; t may be ca ed thereby, ,7, and the tendency as or elk? "Walls of the conrccuicmf. to a minimum if desired, be erial inserted Within (ration of "llllt? spla ning takes escapes. Withthe ators were open the usual custom, d come into contact njury thereto, and quantity or acid hcrmore, with the use amount of acid esid when discharged the stack, forms a n1 for greater seriously inmy improvements, the steam Will be and the escape of or into the atmoseliminated, F or 1 construction of the acid are being cirections, surfaces itors aoove the acid A the steam,the unimitted by the Wall flow down into the n, the vapor escaping or: to the next concenianner the steam resulting t of the acid under d from the latter through the elbow entrator to another will be reverse to from one concen 14ft hand or starts, the steam Will into a drum or remay be discharged tom or me L concentrai are other parts of the 33h as heretofore einlo ted for any deshed useful purwill be subjected to a considerable degree of heat from the products of combustion flowing through the flue or passage 8, and it is important that the upper portions of the concentrators be protected against such a degree of heat. For this purpose, I may employ suitably formed blocksor slabs of lire proof material, such as indicated, at 4A.

A supply tank Fig. 61 01 the Weak acid (about to 61 degrees Be.) to be concentrz ted is provided and is connected With a tank 16, a suitable valve, such forexample as'that illustrated at 47, being provided to control the flow of acid into said tank 46.

.lhe tank 46 is provided with discharge outlets 48, 49 and the flow of acid through these outlets is controlled by a manually operable valve 50 and an automaticallyoperable valve 51, Acid Will be fed from the tank 46, over a deflector 52 into the outer portion of a pan 53. The vertical Wall at the inner end of this pan is provided with a discharge outlet 54 over which a deflector 55 projects, said deflector preferably being provided with a hole which is normally closed by a plug 56. A pipe 57 connects the outlet 54 of the pan 53 With the first or upper concentrator 21 of the series.

At the outer or lower end of the series of concentrators, a discharge pipe 58 is provided and conducts the final. acid product to a tank or receiver 59.

In the normal operation of the apparatus, the hot gaseous products or combustion Will pass ,irom the combustion chamber through the opening 11 at a temperature of about 2600 F. and the same will be divided into several streams by means of the spaced bars 12. 'ihese streams of gaseous products of combustion Will commingle, in the flue 7, With streams of products of combustion entering between the bars 15 at a temperature of about 700 F.,the mixture of the two streams of hot products of combustion in the flue 7 raising the temperature of the Warm gases from flue 10 and lowering the temperature of the hot gases-from flue 11 to about 1400 F., which is a temperature that,

the concentrators will safely stand. The hot gases enter ng the inclined flue 8 under the concentrators, will heat the latter andv cause the Water to be boiled out of the acid which they contain,- said Water passing in the form of steam or vapor'frompne concentrator to another and finally to the drum 43' as previously explained. By the time that the hot gaseous products shall have reached the right hand end of the flue 8, its temperature will have been reduced to aboutv 700 F. About two thirds of-these gaseous products Will descend through the flue 9 to the flue and from the latter, (in the form of streams) to the fine 7 over the combustion chamber, with the result above are explained. About one-third oi the gaseous products ill pass from the tine 8 to the stack. The proper relative proportions of gaseous products taking; the two routes from the line 8, so as to insure circulation through the lines 9 and 10, may be regulated by a suitable damper such as indicated at 60. and the damper 18 may also be employed. to assist in such regulation of the circulation of the gaseous products.

It, will be observed that with my improved apparatus, the first concentrators of the series containing the weak acid, are subjected first to the hottest products of combustion and that the temperature of the latter will gradually decrease as they reach the end of the series of concentrators which contain the concentrated acid. The weak acid thus subjected to the highest temperature will contain considerable water to be vaporized and willlherefore utilize the heat very rapidly. Furthermore, when the high degree of heat strikes the first concentrators, cold acid is being admitted which must be heated to the boiling point, and consequently the most violent. splashing does not take place in the first concentrator. I 'Again the introduction of the high temperature of the gaseous products oicombus tion at the end of the apparatus where the weak acid is admitted, will cause the tom perature ct said gaseous products to tall rapidly as they travel throi'ig-h the line or passage 8 under the concentrators toward the end of the apparatus Where the concentrators containing the most highly condensed acid is located. Thus the bulk of the work for effecting concentration will be accomplished where the acid contains a considerable amount of water and as the acid passes through the concentrators to the discharge cnd of the apparatus, the temperature of the heating gaseous products becomes .reduced several hundred degrees, thereby allowing the strong acid, which contains very little water, to boil more slowly and decoruposition of a larger portion of the acid excessive heat will be avoided. Thus I am enabled to accomplish properly, about twice as much work as could be accomplished in less satisfactory manner, were the concentrators at the discharge end oi the apparatus subjected first to the highest temperature.

The acid to be concentrated reaches the first concentrator at the upper end of the series at about to 61 degrees and leaves the last concentrator at approximately degrees B6. [is the acid flows from one concentrator to another. its degree of temperature as well its degree of concentration will incrcasc. so that in some instances when the highest degree of concentration is reached, the temperature of the discharged an rm acid may reach 600 A. i he acid is discharged .0211 the final concentrator the pipe 8 into the receiver 59 as or seated.

Inorder to cool the lower portion 0* receiver 59 same is inclosed by a najackct 61. A small rersel 62 cles l bottom is inserted into the upper portion the receiver 59 where it will a "t perature of the discharged in and is so disposed within the receiv as not to interfere with access to the latter should it becomenecessary to loosen incrustation or sediment therein. The vessel 8:2 is made of material which shall be proof against both acid and mercury and is partially filled with so 'thelatter nietal'. Thermostat 63 is: also aisposed within the vessel 59, the same being secured at its lower end to a bracket dependinginto the vessel and its upper end projecting above the top of the latter. e vessel 6:2 is supported by a bracket 65 Wn. carries to adjustable contacts 66'67 between which the upper projecting end of the thermostat is disposed. The purpose of the thermostatic Tcircuit controlling devices 5 above described, is to provide means for automatically controlling the feed of acid to the apparatus as the temperature of the condensed acid at the discharge end of the apparatus rises above or falls below a pre" 9 determined in constructing the devices whereby the main teed valre 51 is automatically controlled, I provide a bracket 65 on which shaft 66 carrying a ratchet Wheel 67*, is we mounted. A pulley 58 is also secured to the shaft 66- ,and receives motion by means of abelt 68 from. any suitable slow running motor, not shown. A yoke 69 having ratchet teeth 70-i'l on its opposing inner 105 faces receives the ratchet wheel or pinion lower arm of this yoke is pivotally connected to the stem ot the iced valve and the upper arm of said yoke is pirotally ttached to one end of a bar or link 72. The other ODCiOl the bar 72 is pivoted to one end of a shait 73 which is mounted to more longitudinally through plates 7l75 locate i upon the bracket 65. Electra-magnets '?6-77 are secured to the respective brackets i l-J5 and an armature 78 is secured to the shaft ?3 so as to be disposed between the poles of the respective Une terminal of the coil of magnet 76 is connected by a conductor 79 with the contact 86., and one terminal of the coil of magnet 77 connected, by a conductor with the contact 67. The other terminals of the coils of the two magnets 76 and 77 are connected to one terminal of a battery 81, the other terminal of this battery being connected. l a conductor S2 with the thermostat 63.

Formally the armature 78 will be dis posed centrally between the poles of the two magnets and the yoke 39 will be held in. such ture of the eoinrentrated a into the recei er 5 iucrei" s inch is deslz'ed, the thermostat deflected to the left and the ll". thiis closing the circuit of the 35 and causing movement of the ar- 1' and shaft 73 to the right.

This the shaft 73 will be transmitlldl linl: 72 to the r: tchet 1 the teeth 70 thereof to en- As this wheel is t yoke to move the same crate the valve 51 to m- "he apparatus, concentrated il below the l he: do contact gnet 7a the vein; eel 67 and the crease the teed not ice sirto unt of re apparatus ill , y ilCltt vvhi ch mation of feed of en the acid dis- 19 gets too Weak, 'perature to fall, the above described -l nc valve to apparatus,

be auton'iatiill its upper I J. 031 said lo steam of di 1+ into acid norn ially hopper 8? con the consequent ion is reacne iron held ueh e 5.

1' may adjust the glass cover en the nighet tering the concentrators Well as the sulte t iron by formation in small quantll. ties 'fmm the concentrators, after L118 con- C0! tration has been r: 'ised to a degree Where these sulfates are no longcrsoluhle, will form hard iuerustation on the inner surface of the concentrators and it allowed to run long enough, this incrustation will become a non-conductor of heat and allow the \valiS ot the concentrators to become overheated -d broken. In accordance with the practice retofore employed,--aftcr the apparatus is been running for a certain length of lime, it is shut. down and the concentrators 'emoved and cleaned. My improvements contemplate means whereby such practice as above described may be avoided and the c0ncentrators cleared of incrustation without necessity of removing them. The instrumentalit-ies and the method which I employ for this purpose will now he explained.

A tank 90 is provided to contain chamber acid (which has a strength of about t? or d8 degrees and connect the same with a tank 91,-;1 suitable valve being provided in the pipe or duct connectin these tanks.

*ail operable valves 93-9l are provided fill mnlrollingg the feed of chamber acit to the pan and through the pipe 57 to the first of the series of concentrators. At the discharge end of the apparatus, a pipe 95 is located and provided With a hopper or funnel 90 with which the pivoted funnel 85 may be caused to coi'umuulcatc. The pipe 95 is connected with a suitable storage tank 9? lVhen it becomes necessary to clean the concentrators, the 'alve ell" or the valves 50, 51 or all oi? them will he closed to stop the feed of the degree acid from the supply tank and open the valves 92- I i---.)-l so as to cause the flow of the chamacid from the tank 90 to the concentrators. The W at acid is thus -fed to the concentrators without stopping the operation of the apparatus and. the amount of feed can be easily regulated by manipulating the valves 93 ll hile the Weak chamher acid is being partially concentrated during its passage through the apparatus, it will dissolve incrustatlon in the comet;- tors and in the wipes and vessels through which it passes or its way from the concentrators to the storage tank 9'? and it will jiso dissolve any "sediment which may have )GP 1 .;er.med. Thus the apparatus will be ed. ll hile the apparatus heing op- T'OOil Work in concentrating the chamecome cleaned, the va ves 92-93-9lmay 5 icul. After the apparatus shall have "ited for cleaning; purposes, itis doing v the concentration process as previously described.

I do not in this application, claim the feature herein described involving the clean ing of the concentrators by dissolving the incrustation resulting from high concentration, with the use of a weal: acid, the same being the subject of a divisional ap plication filed by me on the 30th day of December, 1918, and designated by Serial No. 268,872.

Various changes might be made in the details of construction of my invention Without departing from the spirit thereof or limiting its scope, and hence I do 'not Wish to restrict myself to the precise details herein set forth.

Haring fully described my invention What I claim as new and desire to secure by Letters-Patent, is:-

1. In apparatus for concentrating sulfuric acid, the combination with a connected series of concentrators and means for feeding acid into the concentrator at one end of the series, of heating means arranged to apply the highest degree of-heat to the concentrator into which the acid is fed and then to apply heat to the other concentrators .of the series successively.

2. In apparatus for concentrating sulfuric acid, the combination With an inclined series of connected concentrators, and means for feeding acid to the upper end of said series of concentrators, of means for heating said concentrators successively from the upper to the lower end of the series, the highest degree of heat being applied to the concentrators at the upper end of the'series.

3. In apparatus for concentrating sulfuric acid, the combination with an inclined series of connected closed concentrators, means for feeding acid to the upper end of said series, and means for discharging concentrated acid from the lower end of said series, of heating means, means for supplying the highest degree of heat from said heating means first to the upper end oi the series of concentrators and then supplying heat successively to the remaining concentrators of the series.

4. In apparatus for concentrating sulfuric acid the combination with a furnace structure comprising a combustion chamber and a connected series of dues including a line over the combustion chamber for eii'ecting a continuous circulation of products of eombustim from the combustion chamber and back to the nue over the combustion chamber, of a connected series of concentrators forming the top of one of said flues, a stack connected with one of said fiues, means for f eeding acid to one end of the series ofbiincentrators and means for discharging acid from the other end of aid series of concentrators.

recess? 5. In apparatus for concentrating sulfuric acid, the combination of a furnace structure having a combustion chamber, a bridge Wall forming a vertical flue communicating with the combustion chamber, a flue over the bridge Wall communicating with said vertical flue, a vertical flue the opposite end of the fine over the bridge Wall, and a bottom flue connecting the last-mentioned vertical flue with the first-mentioned vertical due, a stack communicating with the exit end of the fine over the bridge Wall, a connected series of concentrators over the last mentioned fine, means for feeding acid to the end of the series of concentrators nearest the first-mentioned vertical line, and means tor discharging acid from the opposite end of the series of concentrators.

6. In apparatus for concentrating Sill furie acid, the combination of a turna e structure having a bridge Wall and comprising a combustion chamber, a vertical due, a plurality of passages connecting the combustion chamber with the vertical flue, a flue over the bridge Wall communicating at one end with the upper end of said vertical flue, fines connecting the other end of the line over the bridge Wall and the vertical flue and communicating with the latter, a stack communicating with the flue over the bridge Wall, a connected series of concentrators over said last-mentioned flue, means for feeding acid to the end of said series of con centrators nearest said vertical flue, and means for discharging acid from the end of the series of concentrators nearest the stack. i

'7. In apparatus for concentrating sulfuric acid, the combination With a furnace structure having a flue, means for supplying DrOd nets of combustion to one end of said this, and a stack communicating with the other end of said. flue, of a connected series of concentrators disposed over said flue, means for feeding acid to the endof the series of concentrators nearest the end thereof at which the products of combustion enter, and means for discharging acid from the end of said series of concentrators nearest the stack.

8. in apparatus for concentrating sulfuric acid, the combination with a furnace structure, of a plurality of closed concentrators supported in position to be heated by gaseous products oi combustion passing through said im'nace structure, means connecting said concentrators in series, means for feeding acid to the end of the series of concentrators nearest the source of. the gaseous products o'f combustion and means for discharging the comentrated acid from the end of the series of concentrators farthest removed from the source of gaseous products of combustion.

9. In apparatus for concentrating sulfuric acid, the combination with a furnace structure, of a pluraiity of closed communicating concentrators connected in series, means removabl suspending said Concentracto in said furnace structure, means for feeding acid to one end of the series of concentrators, and means for discharging concentrated acid from the other end of said series of concentrators. I

10. The combination with a furnace structure having a flue for gaseous products of combustion, of a connect d series of closed concentrators over said flue, bars on the furnace structure and hangers connecting said bars with the several concentrators of the series and suspending said concentrators over said line.

11. The combination with heating means, of a series of closed containers, elbow spouts connecting said containers, each elbow spout being rigid with one container and having a ball-joint connection with the adjacent container, means for feeding material to be treated into one end of the series of containers, and means for discharging the treated product from the other end of said series of containers.

12. The combination with heating means, or" a series of closed containers, elbow spouts connecting said containers, each elbow spout being made rigid with one container and movably connected with the adjacent container, a bail embracing eachelbow spout and engaging the adjacent concentrator, a spring between each bail and elbow spout, means for feeding material to be treated into one end of the series of containers, and means for discharging the treated product from the other end of the series of containers.

13. The combination with heating means, of a series of closed containers, elbow spouts connecting said containers, each elbow spout trically controlled means for said and a thermostatic device control temperature in in circuit with said electrica ..y controlled means. 7 3

16. The combination 'th series of concentrators, a m ing the same, of a feed o the series, a receiver of the series, b 3118211... same, a yoke having two rock o eooperate with said gear, a connection'bec said yoke and the feed valve, two electromagnets, a longitudinally movab e sl w-rt, an armature carried by said sir it i the poles of the electro-magne bar pivoted at one end to said shaft and tne other end to said yoke, thermostatic C. i e controlled by the temperature in said I "fer, and tric circuits including sai *ice and the coils of said eie 17. The combination 'Wl series of containers, and n the same, of a tank. trolled valve for said teed ta. so tank at the discharge end 0' containers, a thermostatic device contro led by the tenipcratiu'e in said receiver, anoth r feed valve for the feed tank, and mom controlled bv the thermostat for. controll operation of said last-mentioned feed 18. The combination with a series of cornmunicating concentrators, of means feeding acid into one end of said series of con centrators, means for heating concen having movable connection with one or said containers, a bail embracing each elbow spout and engaging one of said containers, an adjusting screw carried by each bail, a spring disposed between each adjusting screw and elbow spout, means for feeding material to be treated to one end of the series of containers, and means for discharging the treated product from the other end or the series of containers.

1%. The combination of a series of connected closed containers, each having a normally closed cleaning and inspection open ing, means or heating said containers, means for feeding material to be treated into one end of said series of containers, and means for discharging the treated product from the other end of said series of containers.

15. The combination with a connected series of concentrators, and means for heating the same progressively from the inlet to the'outlet end of the series, of a feed valve at one end of the appai atus, a receiver at the other end ot the apparatus, e1ec- .a vet? into which said pipe discharges. a vess municating at its lower end a end or the receiver. a portions of said receiver an at the uppercnd of said reset which said spout discharges. pipe, and a ti and into which the first-merit]. discharges.

20. The herein described nu centrating sulfuric a id, consisting plyin acid to one end of a series nected concentrators, applying the n or highest degree of heat to that portion or the series of concentrators at which the fi and heating the remaining concenrs successively "with gradually (lee-reams degrees 0f heat tewerd the end of the s of eeneentraters from which the censen'tmied acid. is discharged.

1. T .s herein described in thOfl of cons1il.- -1rie acid, een isting in pass the acid eregressively through clesecl eeneencreters, feeding acid into we end e: series of concentrators reeevering 21c; PEGQHUJF i'rein the same end the eoncentreters, recovering eeneen- 

